A near capacity 90,000 crowd at Wembley came to show their appreciation of England's run to the semi-finals in Russia for the first time in 28 years.
Kane, who scored six goals in seven games, was presented with the award by England manager Gareth Southgate before kick-off.
To mark the occasion, the Spurs striker wore a special pair of gold boots for the clash with the 2010 world champions.
Despite his haul, Kane has since admitted to being disappointed with his performances in some games at the tournament.
Nevertheless, England boss Southgate retains full faith in his talisman, calling him the best striker in the world.
September 8, 2018